3.4 pH
This is dependent on the specific composition of each must, but for our grapes here in Mid MO, a 1 gram per liter addition (3.785 grams per gallon) will provide the desired effect (0.1 drop in pH). Note that's only for red must: white must requires much less of an addition for the same results.
This is a tough one to determine and takes some experience. The change in pH will not occur immeadiately. The way I started was to do a lab trial, then add HALF of what was calculated from the trial. Then check over the next couple of days.
Ideally the pH is adjusted very first thing. But it's better to get it right and take a couple days to adjust. Just try to keep it early in the ferment if possible.
I do this all the time and rely solely on the taste buds to determine TA.
clyde