Jason (Leon?) wrote, concerning calcium carbonate, "The addition will be
2.2grms per litre as the TA is currently 10.2 grm/ltr. and Ph2.9. what method of addition is appropriate i.e. Direct addition of powder, or dissolved in sample of wine before addition etc."
Leon - before you add carbonate you might want to estimate how much tartaric acid will drop out of the wine with cold conditioning. Use several small samples. Add some potassium bitartrate (cream-of-tartar) to half of the samples. Store a set of samples in the frig. for a day or two (mix these several times). Store another set of samples in the freezer. Then, thaw the freezer samples and retest for acid content. You may find a substantial reduction in %TA with the cold treatment.
Also, you probably should test a sample with the amount of carbonate you intend to add to the bulk wine, degass and retest for %TA and pH.
For the bulk wine I transfer to a large container (lots of gas will be released). I add the carbonate directly to the wine in increments with stirring. Make sure the wine is at room temperature (the reaction will be faster and will have a better chance to go to completion). Position a pH meter probe in the wine. Stop when pH rises to a desired point so you don't overshoot. If pH seems OK add all the carbonate salt that your experiments show is needed.
Bill Frazier Olathe, Kansas