Don wrote, refering to adding various amounts of sulfite to various size containers "It's a possibility I guess but again I think it's easier to do the nitrogen/CO2 then what your recommending." ~I make lots of beer and wine. Over the years I've accumulated many different size carboys, bottles, kegs, etc. With such an assortment there's no need to keep beer or wine in partially filled containers. You mentioned it was a problem adding the correct dose of sulfite to different size containers. My post was just information about an easy way to add doses of SO2 to different size containers.
"SO2 can't be the only method used, you have to minimize headspace/O2 by either topping off or something. Or did I miss something in what you said?" ~With various size containers available it's no problem to rack to full carboys and bottles. I know the volume of these containers so it's easy to select fresh bottles to rack wine into. I keep carboys and bottles filled to within 1/2-inch of the stopper. With barrels I do top up with wine that I've bottled in beer bottles. I find that 10 gallon barrels take about 1 beer bottle of wine every two weeks to stay full.
Several years ago I did lose wine, stored in a beer keg, to oxidation. The keg was first filled with water. The water was displaced with CO2. Then wine was racked into the keg...it didn't totally fill the keg but what the heck...there was CO2 above the wine. Evidently the seal was not perfect and air mixed with the CO2...the wine oxidized. After working all summer in the vineyard, then vinting the wine it's a pain to end up oxidized. This was just the tail end of a batch but I don't use partially filled containers any more.
Bill Frazier Olathe, Kansas USA