PA is a ballpark scale, lots of things the hydrometer can't account for affect actual finished alcohol. I have a PA scale that goes below a S.G. of 1.000; most don't. This one has 0 PA as about 1.002; I always thought 0 PA was set to 1.000 but apparently that is not true. It has a 60 F calibration curve, but that's not it. That would only account for a 0.0007 difference, not 0.0002. This one has 2 PA marks below S.G. 1.000.
When it indicates below 0 PA you have the presence of alcohol which has a S.G. of around 0.79. Where it ends up has to do with the other dissolved solids in the wine; some can be fermentable sugars, some unfermentable sugars, acids etc. Some of that changes during fermentation and stabilization, that's another reason it's only ballpark.
You subtract finished from starting to get close.
If it has a S.G. set of graduations it should indicate 1.000 in distilled water at the calibration temp, which is either 68 F or 60 F.
Joe