Apologies, I missed this. I should set up the newsreader rather than rely on Google...
I have a copy of Zoeckleins et al "Wine Analysis & Production"; in it it describes the AOAC procedure for measuring TA. on page 512 it tells you to remove the CO2 by holding the sample at 60 C in a water bath for 'several minutes'. They considered it a major source of error.
Does CO2 in an aqueous media form carbonic acid? Maybe that's it, but I'm not a chemist, I don't know for sure. That is the way they suggest to drive it out. Margalit says boil and reconstitute.
I'm just trying to get repeatable measurements so I can 'benchmark' my tastebuds so I'm open to correction... :o) Joe